Wednesday 3 June 2015

2.7.2e: make predictions about fluorine and astatine and their compounds based on the trends in the physical and chemical properties of halogens

Reactivity:
  • decreases as you go down the group
  • halogen atoms are trying to gain one more electron to have a full outer shell, so the closer the outer electrons are to the nucleus (smaller atomic radius), the more reactive the halogen
Electronegativity:
  • decreases as you go down the group
  • the smaller the atomic radius, the more attraction the nucleus can exert on electrons
Ionisation energy:
  • decreases as you go down the group
  • more shells = less attraction of the outer electrons, so they can be more easily removed
Melting/boiling points:

  • increases as you go down the group
  • all are simple molecules with weak van der Waals forces, so the bigger atoms are more polarisable and have more electrons, allowing them to have stronger van der Waals forces

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