Wednesday, 3 June 2015

2.13b: discuss the relative effects of different greenhouse gases as absorbers of IR and hence on global warming

The atmosphere is a layer of gases surrounding the earth
  • the troposphere
    • 0-15km above sea level
    • densest layer, contains the most gas molecules per unit volume
  • the stratosphere
    • 15-50km above sea level
    • enriched in ozone molecules, which absorb harmful UV radiation from the sun
Greenhouse gases:

  • trap and re-radiate solar radiation to the Earth, creating the greenhouse effect, which enables life on Earth
    • too many greenhouse gases in the atmosphere, in too-high abundance, causes the enhanced greenhouse effect, which is caused by human activities
  • what is the greenhouse effect?
    • UV and visible radiation from the Sun warms up the Earth
    • the Earth loses energy as infrared radiation
    • greenhouse gases absorb infrared radiation and prevent it from escaping, so less heat energy is lost to space, making the Earth steadily warmer
  • what makes a greenhouse gas?
    • the molecule must have a polar bond, which can absorb infrared radiation
    • eg. N2 and O2 have identical electronegativities, so their bonds are not polar - they are not greenhouse gases
    • eg. CH4 and CO2 do have polar bonds, so are greenhouse gases
  • water is the greatest contributor to the greenhouse effect
  • CFCs may only be present in small concentrations, but they are very stable and take a long time to decompose
  • cattle farming increases the concentration of methane in the atmosphere
    • methane absorbs more IR per molecule than CO2
  • air pollutants:
    • CO2 produced by the combustion of fossil fuels
    • SO2 produced when sulphur (naturally present in fossil fuels) combusts
      • reacts with water in the atmosphere to form acid rain
    • NOx formed when nitrogen and oxygen react together in the high temperatures of car engines
      • can react with water in the atmosphere to form acid rain
      • produces a photochemical smog, which reduces visibility and can cause respiratory illnesses
    • CFCs, used to be widely used in refrigerants and aerosols
      • react with and deplete the ozone layer, allowing harmful UV light to reach the Earth’s surface

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